Alkyne mechanochemistry: putative activation by transoidal bending.
نویسندگان
چکیده
We investigated the use of mechanical stress to bend carbon-carbon triple bonds. Formation of an isoquinoline after reaction with a benzyl azide trap points towards a nucleophilic addition mechanism, differentiating mechanochemical trans-bending of π bonds from the typical reactivity observed for cisoidal bending of triple bonds in strained cyclic alkynes.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 87 شماره
صفحات -
تاریخ انتشار 2014